Deadlifts are by far the biggest movement for that day; I'd personally put them first, regardless of what kind of scheme you end up doing with them. They're the most important exercise, recruiting ~80% of your total musculature.
Be forewarned: they will fatigue you. You might find yourself not as strong on your other exercises afterward, so I'd recommend cutting back on some sets; at least initially.
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Form follows function.
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